THE OZONE-ION PROCESSING IN THE SYSTEMS OF TURNOVER WATER SUPPLY OF PLANTS

Section

Geoecology

Title

THE OZONE-ION PROCESSING IN THE SYSTEMS OF TURNOVER WATER SUPPLY OF PLANTS

Сontributors

A. I. Azhgirevich, Ph. D. (Engineering), All-Russian branch association of employers Ecosfera, This email address is being protected from spambots. You need JavaScript enabled to view it.

Abstract

The bacterial-static preparations from the combinations of «ozone — silver ions» and «ozone — copper ions» are recommended in the paper as a less harmful (from the ecological-hygienic point of view) alternative to the chlorination of water in the systems of turnover water supply of plants. In this process, the ozone performs the functions of an oxidizer and main disinfectant, and the silver ions (or copper ones) work as activators of the bactericidal effect of the ozone and a bacteriostatic agent.

To find the most effective option, two schemes are considered: the first one includes a node of bactericidal handling with the electrolyzer, which is built-in into the main water supply system, the second one pro-vides the application of a portable ionator.

It is established, that from the perspective of the consumption of cop-per and silver, it is the most appropriate to apply the ozone-ion method in the systems of turnover water supply of the relatively small capacity of treated water. However, if you consider the concentration, recommended for chlorine in water disinfectioning, the required quantity of this disinfectant for the system of turnover water supply of a larger capacity, for exam-ple, of 10 million m3 a year, will constitute 15 tons, while the amount of sulfate of copper will constitute 12,5 tons, and in terms of a copper vitriol, it will be 19,5 tons, at the same time the fixed concentrations of copper are less than its maximum concentration limit in drinking water. It is specified, that the choice in favor of this or that finishing disinfectant in the schemes of «ozone — copper ions», «ozone — silver ions» or «ozone — ions of copper and silver» should be determined from a ratio of economic costs and social-and-ecological damages regarding a particular unit.

Keywords

ozone, water supply, bactericidal processing, disinfecting, bacteriostatic.

References

1.  Azhgirevich A. I. Osobennostiprimenenijaozonakakokislitelja-dezinfektanta [Peculiarities of application of the ozone as oxidant-disinfectant]. Problemyregional'nojjekologii, No. 1, 2014. Moscow, Izdatel’skijdom “KAMERTON”, 2014. P. 91—97. (in Russian)

2.  Linevich S. N. Kompleksnajaobrabotkairacional’noeispol’zovanieserovodorodsoderzhashhihprirodnyhistochnyhvod. [Comprehensive treatment and rational utilization of hydrogen sulfide-containing natural waters and sewage]. Moscow, Strojizdat, 1986. 118 p. (in Russian)

3.  Linevich S. N. Okislitel’no-sorbcionnajaobrabotkaprirodnyhistochnyhvod [Oxidative-sorption treatment of natural and waste waters // Water supply and San. technique] // Vodosnabzheniei san. tehnika. 1995. No. 5. P. 17—20. (in Russian)

4.  Samojlovich V. G. Ispol’zovanieozonadljaobrabotkivodyplavatel’nyhbassejnov [Use of ozone for treatment of swimming pool water] // Vodosnabzheniei san. tehnika. 2000. No. 1. P. 19—20. (in Russian)

5.  Kedrov V. S., Rudzskij G. G. Vodosnabzhenieivodootvedenieplavatel’nyhbassejnov. [Water supply and sanitation of swimming pools]. Moscow, Strojizdat, 1991. 160 p. (in Russian)

6.  SanPiN 2.1.4.559—96. Pit’evajavoda. Gigienicheskietrebovanija k kachestvuvodycentralizovannyhsistempit’evogovodosnabzhenija. (Vvedeny s 01.01.98 g.). [SanPiN 2.1.4.559—96. Drinking water. Hygienic requirements to water quality of centralized drinking water supply systems. (Introduced from 01.01.98).].

7.  Tsinberg M. B., Maslova O. G., Berlin Je. M. Opytvnedrenijalokal’nyhsistemochistkipit’evojvody v shkolah g. Oren- burga // Materialy IV mezhdunarodnogokongressa «Voda: jekologijaitehnologija». [The experience of implementing local systems of cleaning drinking water in schools in the city of Orenburg // Proc. of the IV international Congress «Water: ecology and technology»]. Moscow, 2000. 442 p. (in Russian)

8.  Meier J. R., Lingg R. P., Bull R. J. Formation of mutagens following chloration of humic acid. A model for mutagen formation during drinking water treatment // Mutation Research. 1983. Vol. 118. No. 1. P. 25—41.

9.  Goncharuk V. V., Potapchenko N. G., Vakulenko V. F. Ozonirovaniekakmetodpodgotovkipit’evojvody: vozmozhnyepobochnyeproduktyitoksikologicheskajaocenka // Himijaitehnologijavody. [Ozonation as a method of potable water: possible by-products and Toxicological evaluation of // Chemistry and technology of water]. 1995. Vol. 17. No. 1. P. 3—34. (in Russian)

10.       Kancerogennyeveshhestva: Spravochnik (Materialymezhdunarodnogoagentstvapoizuchenijuraka) / Ed. by V. S. Tu- rusova. [Carcinogenic substances: a Handbook Proc. of the international Agency for research on cancer) / Under the editorship of V. S. Turusov.]. Moscow, Medicina, 1987. 336 p. (in Russian)

11.       Krasovskij G. N., Mihajlovskij N. Ja., MarchenkoJu. G. i dr. Metodicheskieosnovyvyboradljagigienicheskihissledovanijprioritetnyhgalogensoderzhashhihsoedinenij, obladajushhihotdalennymibiologicheskimijeffektami // Gig- ienaisanitarija. [Methodical bases of selection for hygienic studies a priority halogenated compounds with distant biological effects // Hygiene and sanitation.]. 1985. No. 10. P. 33—35. (in Russian)

12.       NovikovJu. V., Rumjancev N. I., Midin G. D. Dioksiny v sredeobitanijacheloveka — novajagigienicheskajaproblema [Dioxins in the human environment — a new hygienic problem]. Gigiena i sanitarija. 1994. No. 3. P. 36—40. (inRussian)

13.       Slipchenko A. V., Kul’skij L. A., Mackevich E. S. Sovremennoesostojaniemetodovokislenijaprimesejvodyi per- spektivyhlorirovanija [Modern methods of oxidation of impurities in water and prospects of chlorination]. Himija i tehnologijavody. 1990. Vol. 12. No. 4. P. 326—346. (inRussian)

14.       Jel’piner L. I. O vlijaniivodnogofaktoranasostojaniezdorov’janaselenijaRossii [On the influence of water factor on the health status of the population of Russia] // Vodnyeresursy. 1995. Vol. 22. No. 4. P. 418—425. (in Russian)

15.       Denisova I. A. Primeneniekatalizatorov v sistemahvodopodgotovki, ispol’zujushhihperoksidvodorodaiozon, dljapov- yshenijaihjeffektivno-stiijekologicheskojbezopasnosti: Diss. ... kand. tehn. nauk. 05.17.01 — 25.00.36 [The use of catalysts in water treatment systems using hydrogen peroxide and ozone, to enhance their effectively-making and environmental security: Thesis for Dr. Habil.]. Novocherkassk. 2002. 181 p. (in Russian)

16.       Osnovyhimiiitehnologiivody [Fundamentals of chemistry and technology of water] / Kul’skij L. A.; ed. by Stro- kach P. P.; AN USSR. In-t koll. himiivody im. A. V. Dumanskogo. Kiev: Nauk. dumka, 1991. 586 p. (inRussian)

17.       Gutenev V. V. Baktericidnyetehnologiipovyshenijabezopasnostisistempit’evogovodosnabzhenija: Dis. . d-ra. tehn. nauk (05.23.04 — 25.00.36). [Antibacterial technology to enhance security of drinking water systems. Thesis for Dr. Habil.]. N. Novgorod. 2004. 447 p. (in Russian)

18.       Kul’skij L. A. Serebrjanajavoda.[Silver water] Kiev, Naukovadumka, 1987. 109 p. (in Russian)

19.       Kul’skij L. A. Spravochnikposvojstvam, metodamanaliza i ochistkevody. [Reference book on properties, methods of analysis and purification of water]. Kiev, Naukovadumka. 1980. 1206 p. (in Russian)

20.       Prikladnajajelektrohimija. [Applied electrochemistry 2 ed., revised / Ed. by N. T. Kudrjavceva]. Moscow, Himija, 1975. 552 p. (in Russian)

21.       Terent’ev V. I. Nekotoryekonceptual’nyeaspektydostizhenijabezopasnogovodosnabzhenijaivodootvedenijaTezisydokladov IV mezhdunar. kongressa «Voda: jekologijaitehnologija». [Some conceptual aspects of achieving a safe water supply and sanitation // abstracts of the IV Intern. Congress «Water: ecology and technology»]. Moskva, 2000. P. 426—428. (in Russian)

22.       Slipchenko V. A., Maljarevskij A. P. Ionator LK-28 (IJeM-50) napornogotipa s fil’tramidljadeserebrenijaiosvetlenijavody (Opisanieiinstrukcija k ispol’zovaniju). [Ionizator LK-28 (IEM-50) discharge type with filters for decerebrate and water clarification (instructions for use)]. Kiev: Naukovadumka. 1967. 18 p. (inRussian)

23.       Zhurba M. G., Sokolov L. I., GovorovaZh. M. Vodosnabzhenie. Proektirovaniesistemisooruzhenij. [Water. System design and construction]. In 3 Vols. 2 ed., revised. Moscow, Izd-vo ASV, 2004. (inRussian)